Eu(Ⅲ)(CH_2OHCOO)_3·2H_2O和Eu(Ⅲ)(CH_2OHCOO)_3·phen·H_2O配合物的合成和表征  

Synthesis and Characteriztion of Eu(Ⅲ) Binary and Ternary with Glycollic Acid and 1,10-phenanthroline

作　　者：张宏[1] 田江红[1] 宋之刚[1] 

机构地区：[1]甘肃联合大学理工学院,甘肃兰州730000

出　　处：《甘肃联合大学学报（自然科学版）》2005年第3期43-46,共4页Journal of Gansu Lianhe University :Natural Sciences

摘　　要：用羟基乙酸与稀土元素Eu(Ⅲ)合成了二元配合物,又用羟基乙酸、邻菲啰啉与Eu(Ⅲ)合成了三元配合物.通过元素分析、红外光谱、X射线粉末衍射、热谱、荧光光谱及紫外光谱等测试手段,对其性质进行了研究,从而确定了配合物的组成和结构.In this paper binary and tertiary of Eu(Ⅲ) with glycollic acid and 1,10-phenanthroline in aqueous solution were synthesized,and their elements analyses,infrared spectrum,X-ray powder diffraction,thermal analysis,fluorescence spectrum and ultraviolet spectrum have been investigated.The composition of binary Eu(Ⅲ)(CH_2OHCOO)_3(·2H_2O) and tertiary complexes Eu(Ⅲ)(CH_2OHCOO)_3(·phen·H_2O) have been ascertained.

关 键 词：羟基乙酸 邻菲 罗啉 铕配合物 

分 类 号：O614.33[理学—无机化学]