Synthesis of 7-Azidoacetamido-4,6-Dinitro-Benzofuroxan  

作　　者：王建龙 欧育湘 吕连营 陈博仁 

机构地区：[1]School of Material Science and Engineering, Beijing Institute of Technology, Beijing100081, China,Department of Chemical Engineering, North University of China, Taiyuan 030051, China [2]School of Material Science and Engineering, Beijing Institute of Technology, Beijing100081, China [3]School of Material Science and Engineering, Beijing Institute of Technology, Beijing100081, China,Department of Chemistry, Shijiazhuang College, Shijiazhuang 050035, China [4]School

出　　处：《Journal of Beijing Institute of Technology》2005年第2期196-198,共3页北京理工大学学报（英文版）

基　　金：SponsoredbytheMinisterialLevelAdvancedResearchFoundation(206020102)

摘　　要：7-Azidoacetamido-4,6-dinitro-benzofuroxan has been synthesized from the starting materials of chloroacetyl chloride and m-chloroaniline, and has been characterized by elemental analysis, IR, 1H NMR and MS spectroscopies. The title compound was obtained through the reactions of amidation, nitration, azidation and pyrolysis. Azido group was introduced into benzofuroxan derivative to give the energetic compound of high nitrogen content and high enthalpy of formation. It is hopeful that the title compound can be developed into new energetic material and energetic plastic additives.7-Azidoacetamido-4,6-dinitro-benzofuroxan has been synthesized from the starting materials of chloroacetyl chloride and m-chloroaniline, and has been characterized by elemental analysis, IR, 1H NMR and MS spectroscopies. The title compound was obtained through the reactions of amidation, nitration, azidation and pyrolysis. Azido group was introduced into benzofuroxan derivative to give the energetic compound of high nitrogen content and high enthalpy of formation. It is hopeful that the title compound can be developed into new energetic material and energetic plastic additives.

关 键 词：7-azidoacetamido-4 6-dinitro-benzofuroxan BENZOFUROXAN SYNTHESIS 

分 类 号：TQ560.1[化学工程—炸药化工]