固-液相转移催化法合成N-芳酰基-N-′(4-芳氧基苯基)硫脲衍生物  

Synthesis of N-aroyl-N′-(4-aryloxyphenyl)thiourea derivatives under the condition of phase transfer catalysis

作　　者：魏太保[1] 赵莽焱[1] 李满林[1] 王海[1] 张有明[1] 

机构地区：[1]西北师范大学化学化工学院,甘肃兰州730070

出　　处：《西北师范大学学报（自然科学版）》2005年第4期42-44,51,共4页Journal of Northwest Normal University(Natural Science)

基　　金：国家自然科学基金资助项目(20371040);甘肃省自然科学基金资助项目(031-A21-004);西北师范大学青年基金资助项目(02-08)

摘　　要：在固液相转移催化条件下,以PEG-400为催化剂,通过芳酰氯与硫氰酸铵反应合成了中间体芳酰基异硫氰酸酯;后者不需分离,直接与芳胺反应,高产率获得N-芳酰基-N′-(4-芳氧基苯基)硫脲衍生物.Aroyl isothiocyanate is synthesized by the reaction of aroyl chloride with ammonium thiocyanate under the condition of solidliquid phase transfer catalysis using PEG400 as the catalyst.The later need not to be isolated and reaction with aromatic amine immediately to give NarylN′(4aryloxyphenyl)thiourea derivatives in high yield.The promoting effects of the title compounds on wheat growth are tested preliminary.

关 键 词：N-芳酰基-N'-(4-芳氧基苯基)硫脲衍生物 相转移催化 生物活性 

分 类 号：O621.36[理学—有机化学]