脂肪二酸类手性双噁唑啉配体的合成进展  

Advances in synthesis of chiral aliphatic diacid bis(oxazoline)ligands

作　　者：边庆花[1] 那日松[1] 李锋[1] 刘尚钟[1] 

机构地区：[1]中国农业大学理学院,北京100094

出　　处：《化学试剂》2005年第7期406-410,共5页Chemical Reagents

摘　　要：总结了近年来用于不对称催化的脂肪二酸类手性双唑啉配体的合成方法,该类配体可由丙二酸、乙二酸与丁二酸的酰氯和二酯或二元腈与相应的氨基醇反应得到。The recent advances of synthesis of chiral aliphatic diacid bis(oxazoline)ligands for catalytic asymmetric reactions are reviewed.These ligands were prepared from the nitriles or dicarboxlic acid derivatives of malonic acid,succinic acid,oxalic acid and aminoalcohols.

关 键 词：不对称 双噁唑啉 配体 进展 

分 类 号：O626[理学—有机化学]