多元醇还原制备纳米Co粉及其磁性的研究(英文)  

Preparation of nanometer cobalt particles by polyol reduction process and their magnetic characterizations

作　　者：刘飚[1] 官建国[2] 王琦[1] 张清杰[2] 

机构地区：[1]济南大学材料科学与工程学院,山东济南250022 [2]武汉理工大学材料复合新技术国家重点实验室,湖北武汉430070

出　　处：《功能材料》2005年第7期1122-1125,共4页Journal of Functional Materials

基　　金：Supported by the Key Project of National Natural Science Foundation of China(29904005)

摘　　要：采用二价钴盐为前驱物,1,2-丙二醇为还原剂,用液相还原法制备了晶粒尺寸约为10～13nm、具有面心立方(β相)结构的纯度高、粒度均匀的纳米钴粉,运用XRD、TEM等分析方法对制备的纳米钴粉进行物相和结构形貌的表征,初步研究了多元醇法还原Co纳米粉的反应机理.采用VSM对纳米钴粉进行磁学性能的表征.结果表明,所制备的纳米Co粉在室温下具有铁磁性,并且矫顽力不高(6.282×103A/m).By the polyol reduction process, the nanometer spherical cobalt particles with fcc structure and a crystal size of 10-13 nm, are prepared using the reagents of cobaltous salt as precursor and 1,2-propanediol as reducing agent. XRD, TEM are applied to characterize the phase and morphology of the as-prepared products. The magnetic characterizations of the nanometer β-Co particles are studied by VSM. They are ferromagnetic at room temperature but with small coercivity (6.282 × 103 A/m).

关 键 词：纳米Co粉 多元醇 还原反应 制备方法 磁性 

分 类 号：TB383[一般工业技术—材料科学与工程]