5,10,15,20-四(4′-氯乙酸乙酯基吡啶基)卟啉配合物的合成与表征  

Synthesis and Characterization of 5,10,15,20-Tetrakis(4′- chloride ethyl acetate pyridyl)porphyrin Zn(Ⅱ) Complex

作　　者：崔玉民[1] 

机构地区：[1]阜阳师范学院化学系,安徽阜阳236032

出　　处：《合成化学》2005年第4期375-377,共3页Chinese Journal of Synthetic Chemistry

基　　金：安徽省自然科学基金资助项目(050450301);安徽省"十五"优秀人才培养计划资助项目

摘　　要：5,10,15,20-四(4-吡啶基)卟啉与氯乙酸乙酯反应得到5,10,15,20-四(4′-氯乙酸乙酯基吡啶基)卟啉(产率78.4%),后者与过量的醋酸锌发生络合反应得到新化合物5,10,15,20-四(4′-氯化乙酸乙酯基吡啶基)卟啉络锌(产率88.4%)。其结构经UV-vis,1HNMR,IR和元素分析表征。The new 5,10,15,20-tetrakis(4′-chloride ethyl acetate pyridyl)porphyrin complexing Zn(Ⅱ) was synthetized in 88.4% yield from 5,10,15,20-tetrakis(4′-chloride ethyl acetate pyridyl)porphyrin, which was obtained in 78.4% yield through 5,10,15,20-tetrakis(4-pyridyl) porphyrin reacted with ethyl chloroacetate, reacted with Zn acetate. The structure was characterization by UV-vis, ~1H NMR, IR and elemental analysis.

关 键 词：氯乙酸乙酯 卟啉 合成 络合 

分 类 号：O627.23[理学—有机化学] O626.2[理学—化学]