“栅栏”型卟啉合钴(Ⅱ)络合物的合成与载氧性能  

Synthesis and Studies on Oxygen-carrying Abilities of Picket Fence Cobalt(Ⅱ) Porphyrin Complexes

作　　者：陈坚固[1] 李志贤 顾学民 

机构地区：[1]厦门大学化学系

出　　处：《厦门大学学报（自然科学版）》1989年第2期176-179,共4页Journal of Xiamen University：Natural Science

基　　金：国家科学基金资助课题

摘　　要：合成了一种新的“栅栏”型卟啉合钴(Ⅱ)络合物:中位-四-[α,α,α,α-邻-(3,4,5-三甲氧基)苯甲酰胺苯基]卟啉合钴(Ⅱ)(以Co(Ⅱ)TMOPP表示),并用分光光度法研究它的载氧性能,在室温(～20℃),此化合物在含有咪唑的苯溶液中具有可逆载氧性能。A new Picket fence cobalt(Ⅱ) porphyrin complex, meso-tetrakis -[α,α,α,α-ortho-(3, 4., 5-trimethoxy) benzamide phyeny1]porphyrin cobalt(Ⅱ) (Co(Ⅱ)TMOPP) was synthesized, and its oxygen-carrying abilities were determined by spectrophotometry. This model compound exhibited oxygen-carrying capacity reveraibly in benzene solution coataining imidazole at room temperature (-20℃).

关 键 词：卟啉 钴 络合物 载氧 栅栏型 

分 类 号：O614.812[理学—无机化学]