镍系催化剂合成顺丁橡胶的开发研究  

DEVELOPMENT OF cis-1,4-POLYBUTADIENE RUBBER SYNTHESIZED WITH NICKEL CAIALYST SYSTEM

作　　者：郑友群[1] 陈滇宝[1] 仲崇祺[1] 唐学明[1] 

机构地区：[1]青岛化工学院高分子材料工程系

出　　处：《合成橡胶工业》1995年第2期72-78,共7页China Synthetic Rubber Industry

摘　　要：回顾了Ｎｉ系催化剂的开发研究及应用。重点介绍Ｎｉ系催化剂合成顺丁橡胶的聚合特征，活性中心模型，聚合机理，聚合动力学，以及国内外改进Ｎｉ系催化剂的新进展。The development and application of nickel catalyst system in the synthesis of cis-1,4-polybutadiene rubber were reviewed with 58 references.The polymerization characteristics of cis-1,4-polybutadiene rubber synthesized with nickel catalyst system,active center model,polymerization mechanism,polymerization dynamics,and advances of improving nickel catalyst system were introduced.

关 键 词：镍 催化剂 顺丁橡胶 橡胶 聚丁二烯橡胶 

分 类 号：TQ333.2[化学工程—橡胶工业]