八乙基卟啉与钴（Ⅱ）配位反应的物理化学性质研究  

STUDY ON THE PHYSICAL AND CHEMICAL PROPERTIES IN THE COORDINATE REACTION OF OCTAETHYLPORPHYRIN WITH CO(Ⅱ)

作　　者：曹军[1] 刘盛权 何立芳 石卫 黄素秋[1] 

机构地区：[1]长沙电力学院化学系,福建龙岩师专化学系,湖北襄阳师专化学系,武汉大学化学系

出　　处：《长沙水电师院学报（自然科学版）》1995年第3期263-268,共6页

摘　　要：用光度法研究了八乙基卟啉（ＯＥＰ）与ＣＯ２＋离子的配位反应动力学及热力学．结果表明配位反应对ＯＥＰ为一级，对Ｃｏ２＋离子为级，ＨＡＣ对反应有催化作用．提出了ＯＥＰ与Ｃｏ２＋离子配位反应的可能机理．The coordinate reaction kinetics and thermodynamics of octaethylporphyrin (OEP) with Co(Ⅱ )ion were studied with spectrometric method. Experimintal results show that the reaction is first order for OEP and one half order for Co(Ⅱ )ion, HAc possesses catalytic properties on the reaction. The mechanism of the coordinate reaction was proposed.

关 键 词：卟啉 钴 配位反应 物理性质 化学性质 

分 类 号：O614.812[理学—无机化学]