一种新型拟除虫菊酯的合成  

THE SYNTHESIS OF A NEW SYNTHETIC PYRETHROID

作　　者：肖海波[1] 熊建平 

机构地区：[1]上海第二医科大学化学教研室,湖南郴州科技报社

出　　处：《长沙水电师院学报（自然科学版）》1995年第3期259-262,共4页

摘　　要：报道了一种用１．４－双甲氧甲基苯合成对甲氧甲基苄氯（Ⅰ）的较理想的方法及反式二氯菊酸拆分的方法．还报道了用（±）顺、反、（＋）反式、（－）反式二氯菊酸分与（Ⅰ）合成了相应的拟除虫菊脂Ⅱ、Ⅲ、Ⅳ，并对Ⅱ做了初步的药效试验．This paper describs the synthesis of 4-CH3OCH2C6H4CH2Cl (Ⅰ ) from CH3OCH2C6H4CH2OCH3. The (+ ) trans-and trans (-) 2,2-dimethyl-3-(2',2'-dichloroethenyl ) cyclopropane carboxylic acid were obtained by resolution of the (± ) trans - acids. The (± )cis. trans, (+ ) trans, (-)trans-acids were esterifed respectively with (Ⅰ ) to geve the correspondent esters Ⅱ、Ⅲ、Ⅳ and the effective test of Ⅱ has been done.

关 键 词：杀虫剂 甲氧甲基苄氯 拟除虫菊酯 合成 

分 类 号：TQ453.6[化学工程—农药化工]