多核金属磺化酞菁催化下的环己烯环氧化反应  

Epoxidation of Cyclohexene Catalyzed by Multi-Nuclear Metal Sulfo-Phthalocyanine

作　　者：孙强[1] 张天云[1] 王丽萍 姚小华 苏永成 邵长路[1] 张振权 

机构地区：[1]东北师范大学化学系

出　　处：《东北师大学报（自然科学版）》1995年第1期79-82,共4页Journal of Northeast Normal University(Natural Science Edition)

摘　　要：尝试使用９种多核金属磺化酞菁催化环己烯的环氧化反应，结果表明它们对环己烯在氧气作氧源的环氧化反应有催化作用。通过正交试验，发现以多核磺化酞菁镍（Ⅱ）、多核磺化酞菁钴（Ⅱ）和多核磺化酞菁铁（Ⅲ）的催化活性为佳。Nine multi-nuclear metal sulfo-phthalocyanines had been used as catalysts for epoxidation of cyclohexene. The experiment results showed that they have catalytic activity for epoxidation of cyclohexene with molecular oxygen and multi-nuclear ferric sulfo-phthalocyanine, multi-nuclear cobaltous sulfo-phthalocyanine and multi-nuclear nickelous sulfo-phthalocyanine have better catalytic activity for epoxidation of cyclohexene

关 键 词：多核金属 磺化酞菁催化 环己烯 环氧化 配合物 

分 类 号：O641.4[理学—物理化学]