C_（60）－PNVC光电导功能材料的形态与结构研究  

Studies on the Morphology and Structure of C_(60)-modified Poly-N-vinylcarbazole

作　　者：陈或[1] 黄祖恩[1] 蔡瑞芳[1] 俞宏坤[1] 邵倩芬[1] 蔡同润 赵慧玲[1] 胡德珍[1] 

机构地区：[1]复旦大学化学系金属有机化学实验室,复旦大学分析测试研究中心

出　　处：《分析测试学报》1995年第6期21-25,共5页Journal of Instrumental Analysis

基　　金：国家自然科学基金;上海市科委基金

摘　　要：用高分辨^（１３）Ｃ核磁共振技术与扫描电镜法研究了Ｃ_（６０）修饰的聚乙烯咔唑（ＰＮＶＣ）光电导功能材料。结果表明，Ｃ_（６０）与ＰＮＶＣ共混时彼此间存在快速动态电荷转移行为；Ｃ_（６０）含量对化学修饰的ＰＮＶＣ结构影响显著。最后比较了Ｃ_（６０），ＰＮＶＣ及用金属有机化学法制备Ｃ_（６０）－ＰＮＶＣ共聚物的亚微观形态结构差异。The morphology and structure of C60-modified poly-N-vinylcarbzole(C60-PNVC)were studied by high-resolution NMR using13C as probe and scanning electron microscope(SEM).The results showed that there exists transient charge transfer behavior between C60 and carbazole,and that the C60 content has a significant effect on the structure of C60-PNVC.Finally,the submicromorphological structures of C60, PNVC and C60-PNVC were compared.

关 键 词：碳60 光电材料 聚乙烯咔唑 

分 类 号：TN204[电子电信—物理电子学] O635.1[理学—高分子化学]