15个乙烯-乙烯基化合物共聚物的取代基参数  

Chemical Shift Parameters of the Substituent of 15 Ethylene Vinyl Compound Copolymers

作　　者：田文晶[1] 周子南[1] 冯之榴[1] 

机构地区：[1]中国科学院长春应用化学研究所高分子物理开放实验室,长春130022

出　　处：《分析化学》1995年第12期1376-1380,共5页Chinese Journal of Analytical Chemistry

摘　　要：本文应用取代基参数(SCS)方法处了15个EV共聚物的^(12)C NMR谱.它们是:(1)乙烯-α-烯烃共聚物,即乙烯-丙烯共聚物.乙烯-丁烯-1共聚物,乙烯-4-甲基-1-戊烯共聚物,乙烯-己烯-1共聚物和乙烯-辛烯-1共聚物;(2)乙烯-含氧乙烯基共聚物,即乙烯-甲基丙烯酸N,N-二甲基胺乙酯共聚物,乙烯-丙烯酸甲酯共聚物.乙烯-丙烯酸共聚物,乙烯-乙酸乙烯酯,乙烯-乙烯醇,乙烯-氧化碳共聚物(ECO)(?)乙烯-卤代乙烯共聚物及其它EV共聚物,即乙烯-氯化乙烯共聚物(包含氯化聚乙烯),乙烯-溴化乙烯共聚物,乙烯-苯乙烯共聚物(包含氢化丁二烯-苯乙烯共聚物)和乙烯-丙烯腈共聚物、得到了15种取代基的SCS参数.The substituent chemical shift(SCS) theory is used to treat the 13C NMR spectra of 15 ethylene vinyl compound copolymers(EV). They are: (1) ethylene olefine copolymer including (a) ethylene-propylene copolymer (b) ethylene-1-butene copolymer (c) ethylene-4-methyl-1-pentene coplymer (d) ethylene-1-hexene copolymer (e) ethylene-1-octene copolymer; (2) ethylene vinyl oxygen compound copolymer including (a) ethylene-N, N-dimethyl aminoethyl methacrylate copolymer (b) ethylene-acrylic acid copolymer (c) ethy-lene-acrylic acid copolymer (d) ethylene-vinyl acetate copolymer (e) ethylene-vinyl alcohol copolymer (f) ethylene-carbon monoxide coplymer; (3) ethylene-halogenide copolymer and others including (a) ethylene-vinyl chloride copolymer (and/or chlorinated polyethylene) (b) ethylene-vinyl bromide copolymer (c) ethylene-vinyl cyanide copolymer (d) ethylene-styrene copolymer (and/or hydrogenated buatdiene-styrene copolymer). Finally the SCS parameters of 15 substituents are obtained.

关 键 词：共聚物的核磁振 取代基参数 乙烯 乙烯基 

分 类 号：O632.12[理学—高分子化学] O641.133[理学—化学]