醇体系中新型晶体磷酸锆的合成和表征  

Synthesis and Characterization of a New Type of Zirconium Phosphate Crystal from Alcohol System

作　　者：赵玉娥[1] 宋天佑[1] 徐家宁[1] 徐如人[1] 

机构地区：[1]吉林大学化学系

出　　处：《高等学校化学学报》1995年第2期179-180,共2页Chemical Journal of Chinese Universities

摘　　要：醇体系中新型晶体磷酸锆的合成和表征赵玉娥，宋天佑，徐家宁，徐如人（吉林大学化学系，长春，１３００２３）关键词磷酸锆，合成，表征自１９６４年首次合成磷酸锆晶体［１］以来，人们又合成出多种磷酸锆晶体［２～４］。但在非水体系中合成磷酸锆的工作尚未见报道。本...A new type of zirconium phosphate crystal was synthesized hydrothermally from non-aquous system containing fluoride ions with ethylenediamine as the template agent.The product was characterized by several physicochemical methods.The XRD analysis shows that ZrPO-A crystal is a new compound with unique structure;the SEM photograph exhibits that the appearance of ZrPO-A crystal is flaky;the IR spectrum proves that there are the vibrating peaks of tetrahedral PO4 in ZrPO-A crystal.

关 键 词：磷酸锆 晶体 合成 表征 醇 非水体系 

分 类 号：O614.412[理学—无机化学] O781[理学—化学]