交替马来酸酐共聚物多缩乙二醇酯盐络合物中阳离子－高分子相互作用的研究  

STUDY ON THE CATION-POLYMER INTERACTION OF POLYMER ELECTROLYTES BASED ON AN ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHLENE SIDE CHAINS

作　　者：丁黎明[1] 林云青[1] 周子南[1] 

机构地区：[1]中国科学院长春应用化学研究所

出　　处：《高分子学报》1995年第3期360-364,共5页Acta Polymerica Sinica

基　　金：国家自然科学基金

摘　　要：交替马来酸酐共聚物多缩乙二醇酯盐络合物中阳离子－高分子相互作用的研究丁黎明，林云青，周子南（中国科学院长春应用化学研究所长春１３００２２）关键词高分子固体电解质，离子传输，电子轨道结合能高分子固体电解质（ＳＰＥ）可塑性强，易制成大面积均匀薄膜，并具有...A study of the complexes of BM350 with four different alkali metal salts: LIClO4, NaClO4, LiBF4 and LiCF3SO3 by mid-IR and XPS is presented. The results of mid-IR shows that the coordination of canon to polymer makes the C-O-C band become broader and shift slightly. XPS analysis shows that the O atom of two situations can coordinate to Li+(or Na+) and also that this coordination results in the reduction of the electron orbit binding energy of Cl, F and S.

关 键 词：SPE 离子传输 马来酸酐 共聚物 多缩乙二醇脂 

分 类 号：O632.52[理学—高分子化学] O631.23[理学—化学]