甲基丙烯酸三丁基锡酯辐射聚合动力学过程的研究  

Dynamics of radiation-induced polymerization of TBTM

作　　者：赵秉熙[1] 陈道勇[1] 阎立峰[1] 朱清仁[1] 

机构地区：[1]中国科学技术大学,中国科学院结构成分开放实验室

出　　处：《核技术》1995年第10期630-634,共5页Nuclear Techniques

摘　　要：给出了甲基丙烯酸三丁基锡酯（ＴＢＴＭ）辐射聚合反应的动力学方程，阐述了辐照引发的大致过程。动力学研究表明，该体系辐照聚合仍属于自由基聚合机制，其引发过程则为ＴＢＴＭ的双分子反应。In this paper, the dynamics of the radiation initiated polymerization of tributyltin methacrylate was studied and a dynamics equation was given. The equation has shown that the polymerization proceeded with a radical mechanism. And a double-molecule reaction in the initiation process has been presented in accordance with the dynamics equation.

关 键 词：辐射聚合 聚合动力学 TBTM 

分 类 号：O624.42[理学—有机化学]