三甲基乙酸及三甲基乙酰氯的合成  

Synthesis of Trimethylacetic Acid and Trimetylacetyl Chloride

作　　者：孙志忠 李凤芹 郝文辉 邢有权 

出　　处：《黑龙江大学自然科学学报》1995年第3期92-93,91,共3页Journal of Natural Science of Heilongjiang University

摘　　要：本文采用异丁醇与甲醇在硫酸介质中反应，制备了三甲基乙酸，收率为８５％。然后与三氯化磷反应得到三甲基乙酰氯，收率为８７％，并确定上述二步反应的最佳条件。Trimethylacctic acid, obtained by reaction of isobutanol with formic acid in the presence of sulfurric acid in 85% was treated with phosphorus trichloride, toyield trimethylacetyl chloride in 87%. The best conditions of the reaction were reported.

关 键 词：三甲基乙酸 三甲基乙酰氯 合成 聚乙烯 引发剂 

分 类 号：TQ225.122[化学工程—有机化工] TQ225.26