卟啉和卟啉铜分子的成膜特性和UV－Vis光谱表征  

Forming-film Properties and UV-Vis Spectroscopic Characterization of Porphyrin and Copper Porphyrin

作　　者：王海水[1] 王新平[1] 金日镇[1] 席时权[1] 

机构地区：[1]中国科学院长春应用化学研究所应用谱学实验室

出　　处：《Chinese Journal of Chemical Physics》1995年第1期62-65,共4页化学物理学报（英文）

基　　金：国家自然科学基金

摘　　要：合成了５，１０，１５，２０－四（对－异戊酯苯基）卟啉及其铜配合物，研究了它们在气液界面的成膜性质，制备了上述化合物的ＬＢ膜，利用ＵＶ—Ｖｉｓ光谱对化合物在ＬＢ膜结构中的取向进行了表征．研究结果表明．两种化合物在界面上的成膜性质和分子环面在ＬＢ膜结构中的取向均受到铜离子配位的影响．Abstract tetra (p-isoamoxycarbonphcnyl) porphyrin (abbriviated as H2IAPP) and its copper complex (CuIAPP) were synthesized and their structure were verified by elemental anylysis and spectral date. The forming-film properties at air-water interface and molecules orientation in LB films of CuIAPP and H2IAPP were studied. The results were compared.

关 键 词：卟啉 铜配合物 LB膜 UV-VIS光谱 

分 类 号：O484.1[理学—固体物理] O626.13[理学—物理]