氮杂冠醚中间体二氨基芳醚制备的新方法  

The new preparing method for diamino aromatic ethers as the intermediate in preparation of aza-crown ether

作　　者：韩江华 赵明根 李永绪 白宝林 

机构地区：[1]忻州师范专科学校化学系

出　　处：《化学试剂》1995年第1期49-50,共2页Chemical Reagents

摘　　要：用５０％水合肼，在ＦｅＣｌ３·６Ｈ２Ｏ及活性炭的催化作用下，还原制得了８个开链冠醚桥连的二氨基芳醚。还原产率７７％～９２％之间。Eight diamino aromatic ethers containing acyclic crown ether were prepared by catalytic reduction of the corresponding nitro compounds with 50%bydrazine in the presence of iron (Ⅲ) chloride and active carbon. The yield of the diamino aromatic ethers was from 77% to 92%.

关 键 词：二氨基芳醚 氮杂冠醚 还原 

分 类 号：O625.322[理学—有机化学] O626.5[理学—化学]