超微盘电极线性扫描伏安法准稳态准可逆波理论  

The Theory of Quasi-steady-state Quasi-reversible for Linear Sweep Voltammetry at Ultramicrodisk Electrode

作　　者：金葆康[1] 张祖训[1] 周佳海[1] 

机构地区：[1]南京大学化学系,南京210093

出　　处：《化学学报》1995年第4期357-361,共5页Acta Chimica Sinica

基　　金：高等学校博士学科点专项科研基金资助项目

摘　　要：本文提出超微盘电极上线性扫描准稳态准可逆伏安曲线表达式.并用铂超微盘电极、(NH_4)_2Fe(SO_4)_2-lmol.dm^(-3)H_2S0_4体系进行了验证,理论与实验相符.The equation of quasi-steady-state quasi-reversible wave for linear sweep voltammetry at ultramicrodisk electrode is described and the behaviour of voltammetric wave is studied. Experimental results are in good agreement with the theoretical for the oxidation of (NH4)2Fe(SO4): in 1.0mol·dm-3 H2SO4 solution.

关 键 词：超微盘电极 伏安法 准稳态 准可逆波 

分 类 号：O657.14[理学—分析化学]