β-CD与间羧基苯磺酰氯及Fe^(3+)构筑氧化还原酶  

Synthesis of Ferric Coordination Compound of Bis (6-O -m-Carbonyl Benzenesulfonyl)-β-Cyclodextrin with Catalysis of Oxidoreductase

作　　者：丁志刚[1] 刘学群[1] 詹国庆[1] 古元冬[2] 杨向东 

机构地区：[1]中南民族学院化学系,武汉430073 [2]中国药科大学 [3]湖北医药工业研究所

出　　处：《化学学报》1995年第6期578-582,共5页Acta Chimica Sinica

摘　　要：用β-CD与间羧基苯磺酰氯及三氯化铁反应,制得了双(6-氧-间羧基苯磺酰基)-β-CD·Fe^(3+)配合物,以此配合物作催化剂,将苯甲醇高速率氧化成苯甲醛和苯甲酸,其反应速率是三氯化铁的1.4×10~4倍.As β-cyclodextrin reacted with m-carbonyl benzenesulfonyl chloride in solution of pyridine at 80℃ , bis(6-O-m-carbonyl benzenesulfonyl)-β-cyclodextrin, which was characterized by 1H-13C NMR, IR spectra and elemental analysis, was obtained. The ferric coordination compound of this new product could effectively catalyse benzal alcohol oxidized into benzaldehyde and benzoic acid. The catalytic rate was 1.4× 104 times as much as that FeCl3 catalysing the same reaction.

关 键 词：铁 配合物 氧化还原酶 羧基苯 磺酰氯 

分 类 号：Q554[生物学—生物化学] O625.34[理学—有机化学]