2′－胺基－6′－（二乙胺基）萤烷的晶体结构研究  

THE CRYSTAL STRUCTURE OF 2'-AMINO-6'-DIETHYLAMINO-FLUORAN

作　　者：陈红丽[1] 孙命[1] 刘景旺[1] 刘小兰[1] 缪方明[1] 

机构地区：[1]天津师范大学晶体化学研究所

出　　处：《化学研究与应用》1995年第4期418-421,共4页Chemical Research and Application

基　　金：21世纪-青年科学基金

摘　　要：２′－胺基－６′－（二乙胺基）萤烷的晶体结构研究陈红丽，孙命，刘景旺，刘小兰，缪方明（天津师范大学晶体化学研究所天津３０００７４）关键词萤烷，晶体结构萤烷类化合物是现今各国集中研究的一类压敏色素，用于压敏复写纸的制造，特别是随着电子技术和计算机技术的...The title compound was synthezised and its crystal structure was determined by X-Ray difraction.It is found to belong monoclinic system,space group P21/a,crystallographic data as follows:a =14.150(4),b=10.309(4),c=14.197(2),β=110.78°,V=1936.1(1),z=4,D_c=1.325g/cm￣3,Mr=386.45,R=0.09,F(000) = 81 6,μ=0.94cm￣(-1).The C─O bond in the five-memberedlactone ring in the molecule is 1.57,which is longer than the usual lactone C─O single bond。Sowhen reacted with acidic substance,the C─O bond ruptures to tive the fluorescent form of themolecule and simultaneously the colour of the compound changes to red.

关 键 词：萤烷 晶体结构 胺基 乙胺基 压敏色素 

分 类 号：TQ638[化学工程—精细化工]