Synthesis and Crystal Structure of Complex [Cdq_3][Cd(qH)_3](ClO_4)CH_3OH (q=8-Quinolinolate, qH= 8-Quilinolinol)  

作　　者：SHI Jing-Min ZHANG Xia LU Jian-Jun CHEN Yu-Qin MA Jian-Ping LIU Lian-Dong 

机构地区：[1]Department of Chemistry, Shandong Normal University, China,Jinan 250014

出　　处：《Chinese Journal of Structural Chemistry》2005年第8期913-916,共4页结构化学（英文）

基　　金：This work was supported by the National Natural Science Foundation of China (No. 20271043) and Natural Science Foundation of Shandong Province (No. Y2002B10)

摘　　要：The mono-nuclear complex [Cdq3][Cd（qH）3]（ClO4）CH3OH has been synthesized by 8-quinolinol and hydrated cadmium perchlorate in methanol solution. The crystal belongs to triclinic, space group P/ with a = 11.1449（15）, b = 13.3334（18）, c = 17.654（2）A°,α = 85.555（2）, β= 88.497（2）, γ= 75.681（2）°, V = 2534.1（6） A°^3, Z = 1, C110H86Cd4Cl2 N12O22, Mr = 2448.41, Dc =1.604 g/cm^3, F（000） = 1232 and μ = 0.961 mm^-1. The structure was refined to R = 0.0387 and wR =0.0973 for 7775 observed reflections （1 〉 2σ（I））. In this crystal there exist two independent mononuclear complexes of [Cdq3]^- and [Cd（qH）3]^2＋. Each cell contains two [Cdq3]^- anions, two [Cd（qH）3]^2＋ cations, two ClO4^- anions and two methanol molecules.The mono-nuclear complex [Cdq3][Cd（qH）3]（ClO4）CH3OH has been synthesized by 8-quinolinol and hydrated cadmium perchlorate in methanol solution. The crystal belongs to triclinic, space group P/ with a = 11.1449（15）, b = 13.3334（18）, c = 17.654（2）A°,α = 85.555（2）, β= 88.497（2）, γ= 75.681（2）°, V = 2534.1（6） A°^3, Z = 1, C110H86Cd4Cl2 N12O22, Mr = 2448.41, Dc =1.604 g/cm^3, F（000） = 1232 and μ = 0.961 mm^-1. The structure was refined to R = 0.0387 and wR =0.0973 for 7775 observed reflections （1 〉 2σ（I））. In this crystal there exist two independent mononuclear complexes of [Cdq3]^- and [Cd（qH）3]^2＋. Each cell contains two [Cdq3]^- anions, two [Cd（qH）3]^2＋ cations, two ClO4^- anions and two methanol molecules.

关 键 词：crystal structure cadmium complex 8-quinolinol 

分 类 号：O614.242[理学—无机化学] O641.4[理学—化学]