Structure and Transesterification Reaction of Methyl 3-(Phenyldihalostannyl)propionates  

作　　者：Lai Jin TIAN Qing Sen YU Li Ping ZHANG Yu Xi SUN 

机构地区：[1]Department of Chemistry, Qufu Normal University, Qufu 273165 [2]Department of Chemistry, zhejiang University, Hangzhou 310027

出　　处：《Chinese Chemical Letters》2005年第8期1010-1012,共3页中国化学快报（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(No.20173050);Natural Science Foundation of Shandong Province(No.Z2002F01).

摘　　要：The title compounds, PhX2SnCHECHECO2Me （X = C1, 1a; Br, 1b; I, 1c）, readily underwent transesterification into the corresponding analogues, PhX2SnCH2CH2CO2R when reacted with an alcohol ROH. The structural features of these compounds were described, and the possible mechanism of the novel transesterification was suggested.The title compounds, PhX2SnCHECHECO2Me （X = C1, 1a; Br, 1b; I, 1c）, readily underwent transesterification into the corresponding analogues, PhX2SnCH2CH2CO2R when reacted with an alcohol ROH. The structural features of these compounds were described, and the possible mechanism of the novel transesterification was suggested.

关 键 词：Organotin dihalide 3-（phenyldihalostannyl）propionate transesterification reaction crystal structure. 

分 类 号：O623.624[理学—有机化学]