Synthesis and Magnetic Properties of Polyamide Complex Containing Bithiazole Moieties  

作　　者：Hong Zhou GAO Wei Lin SUN Zhi Quart SHEN 

机构地区：[1]Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027

出　　处：《Chinese Chemical Letters》2005年第8期1113-1116,共4页中国化学快报（英文版）

基　　金：The authors are indebted to the financial support of the National Natural Science Foundation of China(No:20374044,20434020).

摘　　要：A new polyamide containing bithiazole moieties （PTA） was synthesized by the polycondensation of 2, 2＇-diamino-4, 4＇-bithiazole （DABT） and oxalyl chloride. The polymer complex was prepared from PTA and NdC13 in DMSO. They were characterized through IR and elemental analysis. The preliminary magnetic properties of the complex PTA-Nd^3＋ was investigated, it was found that the material is a ferromagnet at low temperature.A new polyamide containing bithiazole moieties （PTA） was synthesized by the polycondensation of 2, 2＇-diamino-4, 4＇-bithiazole （DABT） and oxalyl chloride. The polymer complex was prepared from PTA and NdC13 in DMSO. They were characterized through IR and elemental analysis. The preliminary magnetic properties of the complex PTA-Nd^3＋ was investigated, it was found that the material is a ferromagnet at low temperature.

关 键 词：POLYAMIDE BITHIAZOLE rare earth ion magnetic property. 

分 类 号：O633.22[理学—高分子化学]