二茂铁甲醛的乙二胺双西佛碱金属配合物的合成与表征  

Synthesis and Characterization of Metal Complexes of Formylferrocene Schiff-base with Ethylenediamine

作　　者：刘惠民[1] 边占喜[1] 张景林[1] 李保国[1] 

机构地区：[1]内蒙古林学院,内蒙古大学化学系

出　　处：《内蒙古大学学报（自然科学版）》1995年第1期63-66,共4页Journal of Inner Mongolia University：Natural Science Edition

摘　　要：用１，６－二（二茂铁基）－２，５－二氮杂己－１，５－二烯与二价钴、镍、铜、锌、镉和汞的氯化物反应，合成了六种新的配合物．探索出了适宜的反应条件，经元素分析，确定了新配合物的组成为：ＬＭＣｌ＿２：（Ｌ＝Ｃ＿５Ｈ＿５ＦｅＣ＿５Ｈ＿４ＣＨ＝ＮＣＨ＿２ＣＨ＿２Ｎ＝ＣＨＣ＿５Ｈ＿４ＦｅＣ＿５Ｈ＿５．Ｍ＝ＣＯ、Ｎｉ、Ｃｕ、Ｚｎ、Ｃｄ、Ｈｇ），通过红外光谱和核磁共振氢谱测定，对配合物的结构进行了表征．ix new complexes have been prepared by the reaction of 1,6-diferrocenyl-2,5-diazahexa-1,5-diene with the chlorides of cobaltous ,nickelous,Cuprous,zinc, cadmium and mercuric in ethylal-cohol at room temperature respectively and the yields are fairly good. They are yellow to brownsolid and all stable in air and water.Their decomposition temperatures are above 200℃, The com-position of these complexes have been confirmed by elemental analysis and their structures havebeen characterized by IR and ￣1HNMR spectra.

关 键 词：二茂铁 西佛碱 配合物 合成 

分 类 号：O627.81[理学—有机化学]