甲酸甲酯胺化合成N－甲基甲酸胺的研究  

Amination of methylformate to N-methylformamide

作　　者：孙党莉[1] 刘京林[1] 江一蛟 

机构地区：[1]化工部西南化工研究院

出　　处：《天然气化工—C1化学与化工》1995年第4期29-32,共4页Natural Gas Chemical Industry

摘　　要：阐述了甲酸甲酯与－甲胺胺化合成Ｎ－甲基甲酞肢的新方法。从试验结果了解该胺化反应的性能，提出了较为合理的反应机理，并对其反应动力学作了讨论。探讨了该反应的最佳工艺条件。new process for synthesis of N-methylformamide (NMF) by amination of methylformate with methylamine is presented in the arttide. From the experimental result, propertiesof amination have been found out, more reasonable reaction mechanism has been proposedand its reaction kinetics has been discussed.The optimum process conditions have been investigated too.

关 键 词：甲酸甲酯 胺化 甲基甲酰胺 反应机理 

分 类 号：O623.626[理学—有机化学] O641.12[理学—化学]