钾（Ⅰ）（苯并－15－冠－5）新型配合物的合成及性质  

SYNTHESIS AND PROPERTY OF NOVEL COMPLEXES OF (BENZO-15-CROWN-5) POTASSIUM (Ⅰ) ION

作　　者：董文魁[1] 盛芬玲[1] 

机构地区：[1]兰州铁道学院环境工程系,兰州大学分析测试中心

出　　处：《无机化学学报》1995年第1期68-72,共5页Chinese Journal of Inorganic Chemistry

基　　金：甘肃省中青年科技基金

摘　　要：在非水溶剂中合成了苯并－１５－冠－５与碘化钾、硫氰化钾及苦味酸钾形成的三种新型固体配合物，并进行了有关物理、化学性质表征．结果表明，钾（Ⅰ）离子不仅易与苯并－１５－冠－５形成常见的１：２夹心式配合物，而且还能生成稳定的１：１型固体配合物．n this paper, three novel solid complexes of benzo-15-crown-5 with potassium iodine,thiocyanate and picrate respectively, having compositions of K(B15CS)X(X=NCS-, Pic-) and K(B15C5)I·2CO(CH3)2, have been synthesized in nonaqueous solvent, and characterized by clemental analyses, infrared spectra, X-ray powder diffraction analyses, molar conductance measurements. In addition, some differences between two types of complexes (K+: B15CS=1: 1 or 1: 2) are reasonably discussed. If crown to salt ratio is one to one or larger than one to one, 1: 2 'sandwich structure' complexes are isolated, whereas 1:1 complexes form if this ratio is smaller than one to one. The structure of 1: 1 type complexes isolated are not the same as that of the corresponding 1: 2 type complexes.

关 键 词：钾 苯并冠 配合物 性质 合成 

分 类 号：O614.113[理学—无机化学] O626.5[理学—化学]