腙型双冠醚的合成和性质Ⅱ．  

SYNTHESIS AND PROPERTY OF THE HYDRAZONE TYPE BIS-CROWN ETceRS Ⅱ.

作　　者：王志林[1] 陆国元[1] 赵永忠[1] 耿金龙[1] 

机构地区：[1]南京大学化学系,西南京师范大学

出　　处：《无机化学学报》1995年第2期215-218,共4页Chinese Journal of Inorganic Chemistry

摘　　要：４’－甲酰基苯并－１５－冠－５、４’－乙酰基苯并－１５－冠－５分别与肼和芳杂环二肼缩合得到五种新的腙型双冠醚．用电导法研究了它们与碱金属离子的配位性质．Five new hydrazone type his-crown ethers with benzo-15-crown-5 moieties were synthesised by the reaction of hydrazine or aromatic hoterocylic bishydrarine and 4'-formyl or 4'-acetyl benzo-15-crown-5 ethers with good yield. All these new his-crown ethers were characterized by clemental analysis, IR and 1HNMR. The stoichidmetry or the complexes formed by the his-crown ethers with alkali metal canons was determined by electroconductivity titration of the ligand with alkali metal chloride solution.

关 键 词：腙型双冠醚 合成 碱金属 配位 

分 类 号：O626.5[理学—有机化学]