具有亚乙基二硫醚基团的网状聚合物冠醚  

NETWORK POLYMERIC CROWN ETHER WITH ETHYLENE BISTHIOETHER GROUPS

作　　者：陈远荫[1] 孟令芝[1] 殷以华 

机构地区：[1]武汉大学化学系

出　　处：《武汉大学学报（自然科学版）》1995年第6期769-772,共4页Journal of Wuhan University(Natural Science Edition)

摘　　要：具有亚乙基二硫醚基团的网状聚合物冠醚陈远荫，孟令芝，殷以华（武汉大学化学系，武汉，４３００７２）关键词聚合物冠醚，亚铂配合物，硅氢加成催化剂中图法分类号Ｏ６３２·３１通过非冠醚单体的聚合直接合成聚合物冠醚，在一定程度上解决了冠醚化合物价格昂贵、难以回...The ring-opening copolyrnerization of β(β-ethylthioethylthio) ethyl glycidyl ether and diethylene glycol bisglycidyl ether has been investigated. It was found that this reaction could be catalyzed by Bull and the obtained polymer could be co-ordinated with potassium chloroplatinite. The platinum complex is a new kind of hydrosilylation catalyst,and can catalyze the hydrosilylation of olefins with triethoxysilane efficiently.

关 键 词：聚合物冠醚 催化剂 亚乙基二硫醚 环化聚合 

分 类 号：O632.32[理学—高分子化学]