新型梳状高分子固体电解质的研究（Ⅱ）  

Studies on Novel Solid Polymer Electrolytes (Ⅱ)

作　　者：丁黎明[1] 林云青[1] 梁洪泽[1] 汪东梅 王佛松[1] 

机构地区：[1]中国科学院长春应用化学研究所

出　　处：《应用化学》1995年第4期96-98,共3页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金资助项目

摘　　要：新型梳状高分子固体电解质的研究（Ⅱ）丁黎明，林云青，梁洪泽，汪东梅，王佛松（中国科学院长春应用化学研究所长春１３００２２）关键词梳状高分子，ＮａＣＩＯ＿４络合物，固体电解质，离子电导率聚环氧乙烷（ＰＥＯ）可以溶解多种碱金属盐并形成络合物，这种络合物具...The comblike polymer based on methyl vinyl ether/maleic anhydride copolymerwith oligo-oxyethylene chains(BM350)dissolved NaClO_4,forming a homogeneous amor-phous polymer electrolyte. The T_g of the polymer were found to be increased with salt addi-tion. The BM350/NaClO_4 complex at a [Na]/[EO] ratio of 0. 25 exhibited ionic conductivityof 1.03×10￣(-4)S/cm at 25℃,The conductivity of the polymer electrolytes obeys the VTF e-quation and has been discussed in terms of the changes in confugurations.

关 键 词：梳状高分子 固体电解质 离子电导率 

分 类 号：O631.23[理学—高分子化学]