多二茂铁基二氮杂己烷及其过渡金属配合物的合成  

Synthesis of Multiferrocenyl Diazahexanes and Transition Metal Complexes

作　　者：边占喜[1] 王健春[1] 李逢泽[1] 

机构地区：[1]内蒙古大学化学系

出　　处：《应用化学》1995年第2期37-41,共5页Chinese Journal of Applied Chemistry

摘　　要：乙二胺与二茂铁甲醛或双二茂铁甲基氟硼酸盐反应，合成了１，６－二（二茂铁基）－２，５－二氮杂已烷和１，１，６，６－四（二茂铁基）－２，５－二氮杂已烷。它们与过渡金属（Ｆｅ￣（２＋）、Ｃｏ￣（２＋）、Ｎｉ￣（２＋）、Ｃｕ￣（２＋）、Ｚｎ￣（２＋））盐在乙醇或乙醇－二氯甲烷中反应，制得１４种过渡金属配合物。对这些化合物进行了表征。二种配体及其铜配合物用作复合固体推进剂的燃速调节剂时，基本不迁移，而燃速催化效率均超过辛基二茂铁。Two ligands 1,6-diferrocenyl-2,5-diazahexane and 1,1,6,6-tetraferrocenyl-2,5-diazahexane,were synthesized by reacting ethylene diamine with ferrocenyl formaldehydeand biferrocenylmethyl flouroborate respectively. Fourteen complexes of the ligands withFe2+,Co2+,Ni2+,Cu2+ and Zn2+ were prepared. All the compounds have been characterizedby elemental analysis, DTA and IR,1H NMR measurements. The ligands and their cuprouscomplex have been used as burning-rate modifiers for composite solid propellants. No migra-tion was found in composite propellants. The catalytic efficiency of burning-rate was overthat of octylferrocene.

关 键 词：二茂铁基 二氮杂己烷 过渡金属 配合物 

分 类 号：O627.81[理学—有机化学] O641.4[理学—化学]