NaBH_3CN－ZnCl_2体系对含氧二茂铁衍生物的选择性还原  

Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH_3Cn-ZnCl_2

作　　者：林欣欣[1] Lind.,WE 

机构地区：[1]中国科学院广州化学研究所

出　　处：《应用化学》1995年第2期101-103,共3页Chinese Journal of Applied Chemistry

摘　　要：ＮａＢＨ＿３ＣＮ－ＺｎＣｌ＿２体系对含氧二茂铁衍生物的选择性还原林欣欣（中国科学院广州化学研究所广州５１０６５０）ＷＥＬｉｎｄｓｅｌｌ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，Ｈｅｒｉｏｔ－ＷａｔｔＵｎｉｖｅｒｓｉｔｙ，ＵｎｉｔｅｄＫｉｎｇｄｏｍ...NaBH_3CN-ZnCl_2 was applied for the selective reduction deoxygenation of hydroxyland carbonyl groups in ferrocene derivatives under mild condition without affecting on thecarboxy groups.The molar ratio of B/Fe and Zn/Fe,as well as the solvents showed impor-tant influences on the deoxygenation.The possible intermediates were suggested.

关 键 词：氰基 硼氢化钠 二氯化锌 二茂铁衍生物 还原 

分 类 号：O627.81[理学—有机化学] O621.254.2[理学—化学]