Cu（Ⅱ）－Ln（Ⅲ）双核配合物的合成、磁性和抗菌活性  

Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ)Binuclear Complexes

作　　者：焉翠蔚[1] 李延团[1] 廖代正[1] 姜宗慧[1] 王耕霖[1] 

机构地区：[1]曲阜师范大学化学系,南开大学化学系

出　　处：《应用化学》1995年第5期37-41,共5页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金和山东省青年基金资助项目

摘　　要：合成和表征了６种以草酰胺为桥联的异双核配合物Ｃｕ（ｏｘｅｎ）Ｌｎ（ｐｈｅｎ）２（ＣｌＯ４）３（ｏｘｅｎ代表Ｎ，Ｎ′－双（２－氨乙基）草酰胺根阴离子；ｐｈｅｎ为１，１０－邻菲咯琳；Ｌｎ表示Ｙ、Ｌａ、Ｃｅ、Ｎｄ、Ｇｄ和Ｙｂ）．测定了Ｃｕ（ｏｘｅｎ）Ｇｄ（ｐｈｅｎ）２（ＣｌＯ４）３·Ｈ２Ｏ的变温磁化率（４～３００Ｋ）；井用最小二乘法和从自旋Ｈａｍｉｌｔｏｎｉａｎ算符导出的磁方程拟合，求得交换积分Ｊ＝２．３ｃｍ－１；表明配合物中Ｃｕ（Ⅱ）和Ｇｄ（Ⅲ）离子间存在弱的铁磁性超交换作用。测试了配合物的抗菌活性。Six μ-oxamido heterobinuclear complexes,namely Cu(oxen)Ln(phen)2(ClO4)3,(oxen:N,N′-bis(2-aminoethyl)oxamido dianion;phen:1,10-phenanthroline and Ln:Y,La,Ce,Nd,Gd,Yb)have been synthesized and characterized.The variable-temperature mag-netic susceptibility of Cu(oxen)Gd(phen)2(ClO4)3· H2O was measured over 4～300K andthe susceptibility data were least-squares fit to the susceptibility equation derived from thespin HamiItonian operator The exchange integral J was found to be2.3cm-1,indicating that a very weak ferromagnetic spin-exchange interaction operates be-tween Cu(Ⅱ)and Gd(Ⅲ)ions. The antibacterial activity of the complexes were also exam-ined.

关 键 词：铜 稀土 配合物 合成 磁性 抗菌活性 

分 类 号：O641.4[理学—物理化学]