新型三联阳离子表面活性剂的合成  

Synthesis of Novel Trimeric Surfactants

作　　者：李进升[1] 方波[1] 姜舟[1] 江体乾[1] 蒋芳[1] 

机构地区：[1]华东理工大学化学工程研究所化工流变室,上海200237

出　　处：《华东理工大学学报（自然科学版）》2005年第4期425-428,450,共5页Journal of East China University of Science and Technology

基　　金：国家自然科学基金资助项目(20276016);上海市高等学校青年科学基金资助项目(01QN28)

摘　　要：以环氧树脂和十六叔胺为原料,合成了新型三联阳离子表面活性剂,探索了合成低聚表面活性剂的新途径,并对合成工艺进行了优化。对合成的产物进行了化学分析、红外光谱及电喷雾电离质谱分析,证明所得产物为目标产物。结果表明最佳工艺条件为50°C下十六叔胺与环氧树脂物质的量配比为3∶1,将环氧树脂滴加到十六叔胺中,反应7h结束。A novel trimeric cationic surfactant was firstly synthesized with epoxy resin and tertiary amine as main materials. A new method for synthesizing oligomeric surfactants was researched and the synthesis conditions were optimized. The products were analyzed by chemical analysis, infrared absorb spectroscopy and mass spectrometry of electrospray ionization respectively. The results show that under 50 ℃ adding epoxy resin into tertiary amine with the ratio 3 ： 1 and reacting for 7 h are the optimize conditions.

关 键 词：环氧树脂 低聚表面活性剂 叔胺 阳离子表面活性剂 

分 类 号：TQ423.4[化学工程]