六硝基六氮杂异伍兹烷的结构鉴定  

STRUCTURAL IDENTIFICATION OF HEXANITROHEXAAZAISOWURTZITANE

作　　者：欧育湘[1] 陈博仁[1] 贾会平[1] 潘则林[1] 徐永江[1] 

机构地区：[1]北京理工大学化工与材料学院

出　　处：《含能材料》1995年第3期1-8,共8页Chinese Journal of Energetic Materials

基　　金：兵器工业总公司火炸药局资助项目

摘　　要：用ＦＴＩＲ、￣１ＨＮＭＲ、￣（１３）ＣＮＭＲ、ＭＳ（ＣＩ）、ＵＶ及元素分析方法鉴定了作者所合成的六硝基六氮杂异伍兹烷（ＣＬ－２０）的结构，并以ＦＴＬＲ区分了所制得的ＣＬ－２０的四种晶型（α、β、γ及ε）．分析结果证明作者合成的试样的结构与文献报道的ＣＬ－２０的结构式完全相符。The molecular structure of CL-20 synthesized by authors has been identi-fied by FTIR, ￣1HNMR,￣(13)CNMR,CIMS.UV and elemental analysis. The four poly-morphs(α,β,γ and ε)of CL-20 was prepared,and they were characterized by FTIR.The characteristic peaks of the polymorphs in the“fingerprint”region(1200～700cm￣(-1))are in agreement with those reported in literatures. The results show that the structureof CL-20 and its four polymorphs the authors synthesized are undoubted and in high pu-rity.

关 键 词：高能量密度 HEDM CL-20 结构分析 HNHAW 

分 类 号：TQ564.3[化学工程—炸药化工]