钼改性酚醛树脂黏结剂的研究  

Study on Mo-PF Used as Bonding Agent

作　　者：欧阳兆辉[1] 伍林[1] 易德莲[2] 秦晓蓉[2] 曹淑超[2] 王艳[2] 连兰[2] 

机构地区：[1]湖北省高温陶瓷与耐火材料重点实验室,武汉430081 [2]武汉科技大学应用化学研究所,武汉430081

出　　处：《化工进展》2005年第8期901-904,共4页Chemical Industry and Engineering Progress

基　　金：高温陶瓷与耐火材料省重点实验室项目(No.2004A011)。

摘　　要：在反应釜中按一定比例加入苯酚、甲醛、钼改性剂,酸性条件下,加热搅拌2～4h,0.08MPa下真空脱水,得到黏度适中的钼改性酚醛树脂。对钼酚醛树脂进行TG和DSC分析,结果表明:改性树脂固化温度为160℃左右,热分解温度为534.8℃。红外光谱分析表明:钼元素确实已经接枝到酚醛树脂的分子链中。Prescribed amounts of phenol, formaldehyde, molybdenum modifier were added into the reaction kettle, heating and stirring was made for 2～4 h in acid condition. Then the reaction product was dehydrated under reduced pressure of 0.08 MPa until the Mo - PF with appropriate viscosity was obtained. The analysis results for the reaction mixtures with TG and DSC showed that the temperature for its largest curing extent was 160 ℃ and the decomposition temperature of the Mo -PF was 534.8 ℃. Analysis of FTIR proved that molybdenum was successfully grafted on the molecule of PF.

关 键 词：耐火材料 黏结荆 钼改性 钼酚醛树脂 

分 类 号：TQ175.7[化学工程—硅酸盐工业]