含轴手性磺酸配体的镉配合物(英文)  

Cd(Ⅱ) Complex with Disulfonate Atropisomeric Ligand

作　　者：唐云志[1] 周挺[1] 

机构地区：[1]南京大学配位化学研究所配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2005年第9期1435-1436,共2页Chinese Journal of Inorganic Chemistry

基　　金：973项目(No.G2000077500)资助项目

摘　　要：The crystal structure of Cd(BDA)(phen)2(H2O)(H2O)2 (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-bi- naphthylene-4,4′-disulfonate, phen=1,10-phenanthroline)consists of a cadmium center whose coordination envi- ronment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen lig- ands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interac- tions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC: 277921.The crystal structure of [Cd（BDA）（phen）2（H2O）]（H2O）2 （1） （BDA=6,6＇-dibromo-2,2＇-dimethoxy-1,1＇-binaphthylene-4,4＇-disulfonate, phen=1,10-phenanthroline）consists of a cadmium center whose coordination environment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen ligands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interactions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC： 277921.

关 键 词：晶体结构 6 6’-二溴-2 2'-二甲氧基-1.1’-二萘-4 4'-二磺酸 镉 

分 类 号：O614.242[理学—无机化学]