消旋的有机二磺酸三邻菲咯啉锌配合物(英文)  

(Δ,Λ)-[Tris(1,10-phenanthroline)Zn(Ⅱ)] [(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate]

作　　者：黄雪峰[1] 钱坤[2] 

机构地区：[1]南京大学配位化学研究所配位化学国家重点实验室,南京210093 [2]南昌大学稀土中心,南昌330013

出　　处：《无机化学学报》2005年第9期1437-1438,1280,共2页Chinese Journal of Inorganic Chemistry

基　　金：973项目(No.G2000077500)资助项目

摘　　要：Compound Zn(phen)3BDA (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disul- fonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′- binaphthylene-4,4′-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924.Compound [Zn （phen）3] [BDA] （1） （BDA =6,6＇ -dibromo-2,2＇ -dimethoxy- 1,1＇ -binaphthylene-4,4＇ -disulfonate, phen= 1,10-phenanthroline） composes of the anion part （racemic-（R,S）-6,6＇-dibromo-2,2＇-dimethoxy-1,1＇-binaphthylene-4,4＇-disulfonate ） and the cation part which consists of a racemie oetahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC： 277924.

关 键 词：无机手性 6 6’-二溴-2 2’-二甲氧基-1 1’-二萘-4 4’-二磺酸 锌 

分 类 号：O614.241[理学—无机化学]