双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚  

Oxidation of aaaaaaaa-Naphthol catalyzed by binucleus Copper Sulfo- phthalocyanine 1. Preparation of aaaaaaaaa-Naphthoquinone in Ethanol

作　　者：孙强[1] 邓桂胜[1] 姚小华[1] 苏永成 张振权[1] 

机构地区：[1]东北师范大学化学系,吉林长春130024

出　　处：《有机化学》1996年第1期83-87,共5页Chinese Journal of Organic Chemistry

基　　金：吉林省自然科学基金

摘　　要：本文研究了以乙醇为溶剂,CaCl_2为助催化剂,双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚制备α-萘醌的各种因素。提出了可能的反应机理。Various effects on the oxidation of a-naphthpl to a-naphtboquinpne by oxygen with bi-nucleus copper sulfo-phthalocyanine as catalyst and CaCl2 as co-catalyst. were studied. The factors to affect this reaction, such as temperature, the quality of catalyst, co-catalyst and re-action period of time were discussed and a possible reaction mechanism was .also, proposed .

关 键 词：双核磺化酞菁酮 萘酚 催化氧化 萘醌 反应机理 

分 类 号：O625.313[理学—有机化学]