铜酞菁聚甲基丙烯酸甲酯的合成与表征  

Synthesis and Characterization of Copper Phthalocyanine-end-capped poly [Methyl methacrylate]

作　　者：邓建成[1] 殷焕顺[1] 周燕[1] 张海良[1] 

机构地区：[1]湘潭大学化学学院,湖南湘潭411105

出　　处：《精细化工中间体》2005年第4期39-41,共3页Fine Chemical Intermediates

摘　　要：以氯甲基化铜酞菁为引发剂,过渡金属卤化物和配位剂(Cu2Cl2/2,2`-联吡啶)为催化体系,进行甲基丙烯酸甲酯原子转移自由基聚合反应,合成出了铜酞菁聚甲基丙烯酸甲酯,并对其进行了结构表征。A novel copper phthalocyanine-end-capped poly[methyl methaerylate] was synthesized by atom transfer radical polymerization （ATRP） using ehloromethylate copper phthaloeyanine as an initiator and CuBr/2,2- bipydrine as a catalyst. The structure and molecular weight of the copper phthaloeyanine PMMA was confirmed by GPC, IR and UV/VIS spectrum.

关 键 词：铜酞菁 氯甲基化 原子转移自由基聚合 

分 类 号：TQ225.24[化学工程—有机化工]