含高碳糖片断的氨基醇及水解产物的波谱分析  

Structure Elucidation of A Higher Carbon Sugar-Derived Amino Alcohol and Its Hydrolysate by NMR

作　　者：邹大鹏[1] 朱卫国[1] 刘宏民[1] 

机构地区：[1]郑州大学化学系,河南郑州450052

出　　处：《波谱学杂志》2005年第3期277-283,共7页Chinese Journal of Magnetic Resonance

基　　金：国家自然科学基金资助项目(20272054).

摘　　要：利用C10高碳糖合成了具有潜在生物活性的含有高碳糖结构片断的氨基醇,检测了该氨基醇及其水解产物的1H、13CNMR图谱,确证了该类化合物的结构,通过1H1HCOSY,HMQC,HMBC等2DNMR技术对其水解产物的1H和13CNMR数据进行了全归属和较详细的解析.An amino alcohol and its hydrolysate, which are potential glycosidase inhibitors, were synthesized from C10 higher carbon sugar. The structures of these novel higher carbon sugar-derived compounds were elucidated by NMR. The ^1H and ^13C chemical shifts of the hydrolysate of the amino alcohol were completely assigned by 2D NMR techniques including ^H-^H COSY, HMQC and HMBC.

关 键 词：NMR 归属 2DNMR 高碳糖 氨基醇 

分 类 号：O641[理学—物理化学]