Asymmetric Synthesis of N-(Diphenylphosphinyl)furfurylamine by the Enantioselective Alkylation of Furfurylimine  

作　　者：Hai Le ZHANG Xiao Mei ZHANG Xin LI Ai Qiao MI Xin CUI Yao Zhong JIANG 

机构地区：[1]Key Laboratory of Asymmetric Synthesis and Chirotechnology of Sichuan Province and Union Laboraotry of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041

出　　处：《Chinese Chemical Letters》2005年第9期1147-1150,共4页中国化学快报（英文版）

基　　金：The project supported by the National Natural Science Foundation of China(No.20102005)

摘　　要：Optically active N-（diphenylphosphinyl）furfurylamines 2 with good ee values were obtained by the enantioselective addition of dialkylzincs to furfuryl imine 1 in the presence of chiral aminoalcohol derivatives and oxazolines.Optically active N-（diphenylphosphinyl）furfurylamines 2 with good ee values were obtained by the enantioselective addition of dialkylzincs to furfuryl imine 1 in the presence of chiral aminoalcohol derivatives and oxazolines.

关 键 词：ASYMMETRIC DIALKYLZINC N-（diphenylphosphinyl）furfurylarnine. 

分 类 号：O626[理学—有机化学]