Suzuki Coupling Reaction Catalyzed by Cyclopalladated Complexes of Tertiary Arylamines in Ionic Liquid  

作　　者：Hua YI Jin Biao LIU Qiang LI Jie TANG 

机构地区：[1]Department of Chemistry, East China Normal University, Shanghai 200062

出　　处：《Chinese Chemical Letters》2005年第9期1173-1176,共4页中国化学快报（英文版）

基　　金：Project supported by the National Natural Science Foundation of China(No.20172016);Shanghai Science&Technology Council(04JC14032).

摘　　要：Suzuki cross-coupling reaction of phenylboronic acid with aryl halides catalyzed by cyclopalladated complexes of tertiary arylamines immobilized in ionic liquid [Bmim]^＋BF4^- was reported. The catalytic system proved to be efficient and be reused at least 3 times without significant loss of activity.Suzuki cross-coupling reaction of phenylboronic acid with aryl halides catalyzed by cyclopalladated complexes of tertiary arylamines immobilized in ionic liquid [Bmim]^＋BF4^- was reported. The catalytic system proved to be efficient and be reused at least 3 times without significant loss of activity.

关 键 词：Cyclopalladated complex aryl halides Suzuki coupling BIARYL ionic liquid 

分 类 号：O627.31[理学—有机化学] O625.511[理学—化学]