钛硅酸盐分子筛TS－1的合成及表征  

SYNTHESIS AND CHARACTERIZATION OF TITANIUM-SILICATE ZEOLITE TS-1

作　　者：马淑杰[1] 李连生[1] 刘国宗[1] 林文勇[1] 苏克[1] 李莹[1] 

机构地区：[1]吉林大学化学系,长春地质学院测试中心

出　　处：《催化学报》1996年第2期173-176,共4页

摘　　要：钛硅酸盐分子筛ＴＳ－１的合成及表征马淑杰，李连生，刘国宗，林文勇（吉林大学化学系，长春１３００２３）苏克，李莹（长春地质学院测试中心，长春１３００２１）关键词ＴＳ－１沸石，合成，苯酚，催化氧化＊～ｓ－ＺＳＭ－５沸石是Ｓ！Ｉ。。１ｕｅ－１沸石的衍生物，...he synthesis conditions of Ti-Si-ZSM-5 zeolite and its formation patterns were studied by using TPABr, TPAOH, 1, 6-hexanediamine andn-butylamine as a template, respectively. The effect factors on the crystallization of Ti-Si-ZSM-5 zeolite such as silicon sources, titanium sources andpH value were also studied. TS-1 zeolite can be synthesized in the presenceof small amount of Na+ or in the absence of Na+ with the addition of smallamount of TPA+. The physico-chemical properties of the TS-1 zeolite synthesized were determined. The thermal stability of the synthesized TS-1 isgood. The hydroxylation of phenol on the synthesized TS-1 zeolites at 343 Kand pH 5 gives better results, the yield of oxidation products catechol andhydroquinone is 36. 5% and 29. 0% (for template TPAOH), 25. 1% and19. 4% (for 1, 6-HDA), and 24. 0% and 18. 3% (for n-BuNH2) respectively.In this paper, the successful synthesis of TS-1 zeolite using n-butylamine astemplate is first reported.

关 键 词：合成 苯酚 催化 氧化 钛 硅酸盐 分子筛 

分 类 号：TQ424.25[化学工程]