C_（60）、C_（70）与过氧苯甲酰反应的动力学研究  

Studies on the Kinetics of the Reaction of C_(60) and C_(70) with Benzoyl Peroxide

作　　者：胡波[1] 薛万华[1] 张法义[1] 尚振锋 马克勤 臧雅茹[1] 赵学庄[1] 

机构地区：[1]南开大学化学系,山西雁北师范学院

出　　处：《高等学校化学学报》1996年第6期917-919,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：Ｃ_（６０）、Ｃ_（７０）与过氧苯甲酰反应的动力学研究胡波，薛万华，张法义，尚振锋，马克勤，臧雅茹，赵学庄（南开大学化学系，天津，３０００７１）关键词Ｃ_（６０），Ｃ_（７０），动力学Ｋｒａｔｓｃｈｍｅｒ等人［１］的发现使制备宏观量的Ｃ（６０）和Ｃ（７０...The kinetics of the reaction of C_(60) and C_(70) with benzoyl peroxide is studied.The results show that the reaction is first order against fullerenes and the rate constants at 342.2K,348.2K, 353.2 K and 358.2 K were calculated and they are in agreement with experimental results.The rate constant of C_(70) is greater than that of C_(60) and this indicated that C_(70)is more actived than C_(60).The activation energies are 9.275*10￣4J/mol and 8.438*104J/mol for C_(60) and C_(70) respectively.

关 键 词：富勒烯 过氧苯甲酰 反应动力学 碳60 碳70 

分 类 号：O635.1[理学—高分子化学] O621.256.1[理学—化学]