取代苯胺基亚胺二茂铁类化合物莫斯鲍尔谱及分子光谱研究  

STUDIES ON MOSSBAURIC AND MOLECULAR SPECTRA OF IMINOMETHYL FERROCENE COMPOUNDS

作　　者：石进超[1] 郑晓辉[1] 袁宏安[1] 

机构地区：[1]西北大学化学系,西安医科大学

出　　处：《光谱学与光谱分析》1996年第2期106-110,共5页Spectroscopy and Spectral Analysis

基　　金：国家自然科学基金

摘　　要：本文报道了６种取代苯胺基亚胺二茂铁类化合物Ｒ－Ｎ＝ＣＨ－Ｆｅ［－Ｆｅ为二茂铁基，Ｒ为－Ｃ６Ｈ４Ｘ（Ｘ＝Ｈ，４－Ｂｒ，４－ＯＨ，２－ＣＨ３，４－ＣＯＯＨ）及４－ＮＨＣ６Ｈ４ＮＯ２］的Ｍｏｓｓｂａｕｅｒ谱数据，其化学位移分别为（ｍｍ·ｓ（－１））：０．３２３，０．３３２，０．３３８，０．３２４，０．３１５和０．３１０，其四极矩分裂值分别为（ｍｍ·ｓ（－１））：２．２６３，２．２８５，２．２８７，２．２１６，２．２９３和２．２２９并从理论上予以解释。对主要红外吸收峰，紫外及可见吸收谱带进行了指认。The Mossbauric spectra of six iminomethyl ferrocene compounds R-N=CH-Fe [R: -C6H4X (X=H, 4-Br, 4-OH, 2-CH3, 4-COOH) and 4-NHC6H4NO2] have been studied. Their isomer shifts (mm.s-1) were 0. 323, 0. 332, 0. 338, 0. 324, 0. 315 and 0. 310,the quadrupole splittings (mm.s-1) were 2. 263, 2. 285, 2. 287, 2. 216, 2. 293 and 2. 229 have been explained theoretically. The main in frared speaks and UV/VIS bands have been assigned.

关 键 词：二茂铁 红外光谱法 穆斯堡尔谱 苯胺基亚胺 

分 类 号：O627.81[理学—有机化学] O481.4[理学—化学]