纳米SiO_2改性上浆剂对炭纤维复合材料界面性能的影响  

Effects of nano-SiO_2 modified emulsion sizing on the interfacial performance of carbon fiber reinforced plastics

作　　者：杨禹[1] 吕春祥[1] 王心葵[1] 刘鸿鹏[1] 贺福[1] 李永红[1] 宋燕[1] 

机构地区：[1]中国科学院山西煤炭化学研究所炭材料重点实验室

出　　处：《新型炭材料》2005年第3期211-216,共6页New Carbon Materials

基　　金：中国科学院创新方向性项目(KGCX2-SW-204);山西省自然科学青年科技研究基金(20031024);国家自然科学重点基金(50333070)。~~

摘　　要：利用单纤维碎裂法,三点短梁法,扫描电镜(SEM)和动态力学热分析(DMTA)研究了未上浆炭纤维、环氧树脂乳液上浆炭纤维和经纳米S iO2改性环氧树脂乳液上浆炭纤维增强树脂基复合材料(CFRP)的界面性能。结果表明:炭纤维经改性乳液上浆剂和未改性乳液上浆剂上浆后,与未上浆相比,其单纤维复合材料的界面剪切强度(IFSS)分别提高了79%和41%,复合材料的层间剪切强度(ILSS)分别提高了14%和9%。DMTA图谱显示经纳米S iO2改性上浆的CFRP其损耗角正切(tanδ)较未改性上浆的降低18%,玻璃化温度(Tg)高出5℃。说明上浆剂中添加纳米S iO2可使上浆后的CFRP界面黏结性得到显著增强。A single fiber fragmentation test, three-point bend test, scanning electron microscopy and dynamic mechanical thermal analysis （DMTA） were performed to study the influence of nano-SiO2 modified emulsion sizing on the interfacial properties of carbon fibers reinforced plastics （CFRP）. As a comparison, CFRP with and without sizing but not modified by nano-SiO2 were also investigated. Results showed that the interfacial shear strength （ IFSS ） values of the CF with modified sizing and unmodified sizing were increased by 79 % and 41%, respectively, compared to the CF without sizing. The interlaminar shear strength （ILSS） values of the CFRP with modified sizing and unmodified sizing were also increased by 14 % and 9 %, respectively compared to the CFRP without sizing. Furthermore, the loss tangent （ tan δ） of CFRP with modified sizing declined to 18 % and glass transition temperature （ Tg ） was increased by 5 ℃, compared to the CFRP with unmodified sizing in the DMTA chart. So the interfacial adhesion performance of the CFRP with modified sizing by nano-SiO2 was evidently increased.

关 键 词：炭纤维 纳米SiO2 上浆剂 动态力学热分析 界面剪切强度 层间剪切强度 

分 类 号：TB332[一般工业技术—材料科学与工程]