Synthesis and Characterization ofN-(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamic-4-hydroxy-benzoyl Hydrazine Dihydrate  

作　　者：ZHANG Shu-sheng YE Su-juan LI Xue-mei GU Shan-shan LIU Qing 

机构地区：[1]College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

出　　处：《Chemical Research in Chinese Universities》2005年第5期545-548,共4页高等学校化学研究（英文版）

基　　金：Supported by the Program for New Century Excellent Talents in Universities(No. NCET-04-0649);the National NaturalScience Foundation of China(Nos. 20275020 and 20475030).

摘　　要：A new complex of N-（ 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl ） -thiocarbamic 4-hydroxy-benzoyl hydrazine dihydrate, C22 H27 N3 O10S · 2H2 O, was synthesized and its structure was determined by X-ray crystallography and TG/DTG methods. The compound belongs to the orthorhombic system, which crystallizes in space group P212121 , with a = 1. 0275 （ 3 ）, b = 1. 3419 （4）, c = 2. 0234 （ 6 ）, V = 2. 7899 （ 16 ） nm^3, and Z = 4. The hexopyranosyl ring adopts a ^4C1 conformation. All the substituents are at equatorial positions. The molecules are linked into a three-dimensional framework via intermolecular interactions. Atoms O5 and O9 show oositional disorders.A new complex of N-（ 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl ） -thiocarbamic 4-hydroxy-benzoyl hydrazine dihydrate, C22 H27 N3 O10S · 2H2 O, was synthesized and its structure was determined by X-ray crystallography and TG/DTG methods. The compound belongs to the orthorhombic system, which crystallizes in space group P212121 , with a = 1. 0275 （ 3 ）, b = 1. 3419 （4）, c = 2. 0234 （ 6 ）, V = 2. 7899 （ 16 ） nm^3, and Z = 4. The hexopyranosyl ring adopts a ^4C1 conformation. All the substituents are at equatorial positions. The molecules are linked into a three-dimensional framework via intermolecular interactions. Atoms O5 and O9 show oositional disorders.

关 键 词：N-（2 3 4 6-Tetra-O-aeetyl-β-D-glueopyranose Synthesis Crystal structure Characterization 

分 类 号：O629.1[理学—有机化学] O623.752[理学—化学]