Hydrothermal Synthesis and Structure Characterization of Diamine-templated Two-dimenisional Cerium Sulfate,[C_6N_2H_(14)][Ce(SO_4)_2(H_2O)_2]·0·5SO_4·2·5H_2O  

作　　者：XIN Ming-hong WANG Ying ZHU Guang-shan SUN Jin-yu XUE Ming SUN Fu-xing FANG Qian-rong TIAN Ge QIU Shi-lun 

机构地区：[1]State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

出　　处：《Chemical Research in Chinese Universities》2005年第5期619-621,共3页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(Nos.29873017, 20101004 and 29825504) ;the State BasicResearch Project(No.G2000077507).

摘　　要：Open-framework materials are of great interest from both the theoretical and practical points of view due to their catalytic, absorbent, and ion-exchange properties. In the past decade, the study of structurally and chemically diverse open framework solids has been flourishing. A large variety of silicates, phosphates and carboxylates with open-framework structures have been synthesized with organic amines as templates. It has also been demonstrated that other oxysalts such as selenate, arsenate and germanate are used to build up open architectures. As far as the sulfate is concerned,Open-framework materials are of great interest from both the theoretical and practical points of view due to their catalytic, absorbent, and ion-exchange properties. In the past decade, the study of structurally and chemically diverse open framework solids has been flourishing. A large variety of silicates, phosphates and carboxylates with open-framework structures have been synthesized with organic amines as templates. It has also been demonstrated that other oxysalts such as selenate, arsenate and germanate are used to build up open architectures. As far as the sulfate is concerned,

关 键 词：Cerium sulfate Hydrothermal synthesis Crystal structure Two-dimensional layer 

分 类 号：O625.631[理学—有机化学]